Reactivity Documentation
Aryl Halides |
| mixed with |
Metal Hydrides, Metal Alkyls, Metal Aryls, and Silanes |
Summary
- Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive
Details
Aryl Halides
is a reactive group.
Metal Hydrides, Metal Alkyls, Metal Aryls, and Silanes
is a reactive group.
Reactivity Predictions (for each pair of reactive groups)
Metal Hydrides, Metal Alkyls, Metal Aryls, and Silanes
mixed with
Aryl Halides
Aryl Halides
Hazard Predictions
- Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive
LiAlH4 rapidly reduces aryl halides to non-halogenated aromatics at room temperature (H. C. Brown, S. Krishnamurthy, Tetrahedron 35 (1979) 567).
One of the fluorine atoms from pentafluoropyridine can be replaced by hydrogen upon reaction with lithium aluminum hydride, producing 2,3,5,6-tetrafluoropyridine (Boudakian, M. M. 2000. Fluorinated Aromatic Compounds. Kirk-Othmer Encyclopedia of Chemical Technology. (Online)).
Naphthylsodium reacts exothermically with chlorinated biphenyl at elevated temperatures. This reaction could lead to an explosion (MCA Case History No. 565, Case Histories of Accidents in the Chemical Industry, Washington, MCA).
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