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Hazard Predictions

• Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive

Aniline explodes on contact with peroxomonosulfuric acid (Urben, P.G. 1995. Bretherick's Handbook of Reactive Chemical Hazards, 5th Edition. Oxford: Butterworth-Heinemann. pp. 1546; Lewis, R.J., Sr. 1992. Sax's Dangerous Properties of Industrial Materials, 8th Edition. New York: Van Nostrand Reinhold. pp. 254).

Aniline reacts violently with peroxoformic acid (D'Ans, J. et al. 1915. Ber. 48:1136; Lewis, R.J., Sr. 1992. Sax's Dangerous Properties of Industrial Materials, 8th Edition. New York: Van Nostrand Reinhold. pp. 254.). It also reacts violently with dibenzoyl peroxide after an induction period (Bailey, P.S. et al. 1975. Journal of Chemical Education 52:525.).

Aniline and ethylenediamine catalyze the decomposition of diisopropylperoxydicarbonate (Strain, F.J. 1950. American Chemical Society 72:1254).

Aniline reacts exothermically and sometimes explosively with peroxodisulfuric acid, evolving a gas (D'Ans, J. et al. 1910. Berichte. 43:1880; 1911. Z. Anorg. Chem. 73).