Reactivity Documentation
Amines, Phosphines, and Pyridines |
| mixed with |
Acyl Halides, Sulfonyl Halides, and Chloroformates |
Summary
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
- Toxic: Reaction products may be toxic
-
May produce the following gases:
- Hydrogen Halide
- Nitrogen
Details
Amines, Phosphines, and Pyridines
is a reactive group.
Acyl Halides, Sulfonyl Halides, and Chloroformates
is a reactive group.
Reactivity Predictions (for each pair of reactive groups)
Amines, Phosphines, and Pyridines
mixed with
Acyl Halides, Sulfonyl Halides, and Chloroformates
Acyl Halides, Sulfonyl Halides, and Chloroformates
Hazard Predictions
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
- Toxic: Reaction products may be toxic
Amines react with acyl halides to form amides, releasing HCl or HBr as a byproduct (Eller, K., E. Henkes. 2002. Amines, Aliphatic. In Ullmann's Encyclopedia of Industrial Chemistry. Wiley-VCH Verlag GmbH & Co. KGaA. (Online)).
Amines react with phosgene to yield toxic HCl gas (Smith, P. A. S., Open-Chain Nitrogen Compounds, Vol. I. New York: W. A. Benjamin, Inc., 1965, pp. 265).
Butylamine and nitrosyl chloride react to liberate inert N2 gas (Smith, P. A. S., Open-Chain Nitrogen Compounds, Vol. I. New York: W. A. Benjamin, Inc., 1965, pp. 34). Amines may also react with phosgene to liberate N2 gas (Ibid, pp. 245).
Potential Gas Byproducts
- Hydrogen Halide (HX)
- Nitrogen (N2)
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