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Hazard Predictions

• Generates heat: Exothermic reaction at ambient temperatures (releases heat)
• Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive

Methylamine and ethylenediamine have unstated incompatibilities with phosphorus halides (Lenga, R.E., ed. 1988. Sigma Aldrich Library of Chemical Safety Data, 2nd Edition. Sigma Aldrich. pp. 1604, 2283).

Hydroxylamine ignites on contact with phosphorus trichloride and phosphorus pentachloride (Mellor, J.W. 1940. Mellor's Comprehensive Treatise on Inorganic and Theoretical Chemistry. Longmans, Green and Co Ltd. Vol. 8, p. 290).

The interaction between boron trichloride and phosphine is energetic (Mellor, J.W. 1946. Mellor's Comprehensive Treatise on Inorganic and Theoretical Chemistry. Longmans, Green and Co Ltd. Vol. 5, p. 132).

Ethylphosphine explodes on contact with chlorine or bromine (Fire and Explosion Risks, von Schwartz, E., London, Griffin, 1918, p. 324-325).

Aniline, dimethyl amine and pyridine incandesce on contact with fluorine (Hoffman, C. J., Chem. Rev., 1962, 62, 12).