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Hazard Predictions

• Generates heat: Exothermic reaction at ambient temperatures (releases heat)
• Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive

Basic salts such as fluorides may react with polymerization inhibitors (antioxidants) added to stabilize acrylates and acid derivatives. This would increase the likelihood of a polymerization reaction occurring (Bretherick's Handbook of Reactive Chemical Hazards, 5th Edition. Volume 1. Oxford: Butterworth-Heinemann. pp. 515).

HF reacts violently with ethyl acrylate (Lewis, R.J., Sr. 1992. Sax's Dangerous Properties of Industrial Materials, 8th Edition. New York: Van Nostrand Reinhold. pp. 1897).

At high temperature, acrylate polymerization may liberate CO2 and/or other gases. Acrylates and acrylic acids are polymerizable materials and are typically inhibited with low ppm levels of antioxidants (inhibitors) to prevent premature polymerization chain reactions. Many of these inhibitors require dissolved oxygen to be effective. Inhibitor depletion is a function of time and temperature, with higher temperatures increasing depletion rates. These materials are known to be susceptible to destabilization due to low ppm levels of contaminants. Radical generating contaminants such as peroxides and azides are known to initiate monomer polymerization; however, the effects of seemingly benign materials are harder to predict. Therefore, extreme caution should be used in any contamination event. And the material should be presumed to be destabilized until testing and consultation with experts. Uncontrolled polymerization reactions can become adiabatic and lead to a serious runaway reaction with high temperatures and pressures. The general hazards of monomers are discussed in Frurip et al., Process Safety Progress (Vol. 14, No. 2) 1995.