Reactivity Documentation
Oximes |
| mixed with |
Metal Hydrides, Metal Alkyls, Metal Aryls, and Silanes |
Summary
- Flammable: Reaction products may be flammable
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
- Toxic: Reaction products may be toxic
-
May produce the following gases:
- Ammonia
Details
Oximes
is a reactive group.
Metal Hydrides, Metal Alkyls, Metal Aryls, and Silanes
is a reactive group.
Reactivity Predictions (for each pair of reactive groups)
Metal Hydrides, Metal Alkyls, Metal Aryls, and Silanes
mixed with
Oximes
Oximes
Hazard Predictions
- Flammable: Reaction products may be flammable
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
- Toxic: Reaction products may be toxic
Oximes can be reduced to amines with metal hydrides (Cartolano, A. R. and Vedage, G. A. 2004. Amines by Reduction. Kirk-Othmer Encyclopedia of Chemical Technology. (Online); Kammermeier, B. 2000. Reduction. Ullmann's Encyclopedia of Industrial Chemistry. (Online)).
Oximes can be reduced to hydroxylamines using sodium cyanoborohydride (NaCNBH3) or sodium borohydride (NaBH4) (Kammermeier, B. 2000. Reduction. Ullmann's Encyclopedia of Industrial Chemistry. (Online)).
Potential Gas Byproducts
- Ammonia (NH3)
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