Reactivity Documentation
Azo, Diazo, Azido, Hydrazine, and Azide Compounds |
| mixed with |
Acids, Strong Non-oxidizing |
Summary
- Explosive: Reaction products may be explosive or sensitive to shock or friction
- Flammable: Reaction products may be flammable
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
- Toxic: Reaction products may be toxic
-
May produce the following gases:
- Hydrazoic Acid
- Nitrogen
- Ammonia
Details
Reactivity Predictions (for each pair of reactive groups)
Azo, Diazo, Azido, Hydrazine, and Azide Compounds
Hazard Predictions
- Explosive: Reaction products may be explosive or sensitive to shock or friction
- Flammable: Reaction products may be flammable
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
- Toxic: Reaction products may be toxic
Inorganic acids may react with azo compounds to liberate toxic and flammable NH3 and N2 (Predicted).
Combining azides and acids may yield gaseous HN3, which is toxic and flammable (Jobelius, H., H. Hans-Dieter Scharff. 2002. Hydrazoic Acid and Azides. In Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH Verlag GmbH & Co. KGaA (Online); Urben, P.G. 1995. Bretherick's Handbook of Reactive Chemical Hazards, 5th Edition. Volume 2. Oxford: Butterworth-Heinemann. pp. 195).
Organic azides are sensitized by strong acids. (Lewis, R.J., Sr. 1992. Sax's Dangerous Properties of Industrial Materials, 8th Edition. New York: Van Nostrand Reinhold. pp. 312).
Potential Gas Byproducts
- Hydrazoic Acid (HN3)
- Nitrogen (N2)
- Ammonia (NH3)
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