Reactivity Documentation
Azo, Diazo, Azido, Hydrazine, and Azide Compounds |
| mixed with |
Ketones |
Summary
- Flammable: Reaction products may be flammable
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
-
May produce the following gases:
- Hydrocarbons
Details
Azo, Diazo, Azido, Hydrazine, and Azide Compounds
is a reactive group.
Ketones
is a reactive group.
Reactivity Predictions (for each pair of reactive groups)
Azo, Diazo, Azido, Hydrazine, and Azide Compounds
mixed with
Ketones
Ketones
Hazard Predictions
- Flammable: Reaction products may be flammable
- Generates gas: Reaction liberates gaseous products and may cause pressurization
- Generates heat: Exothermic reaction at ambient temperatures (releases heat)
Ketones may be reduced to hydrocarbons by hydrazine (The Wolff-Kishner Reduction), (Morrison, R. 1973. Organic Chemistry. Allyn and Bacon Inc, Boston, pp. 631). Saturated hydrocarbons with fewer than five carbons are flammable gases.
Azoisobutyronitrile explosively decomposed in the presence of acetone. Non-explosive decomposition was observed in the presence of methanol (Bretherick, L. 1996. Bretherick's Handbook of Reactive Chemical Hazards. Fifth Ed. Urben, P.G., Ed. Butterworth-Heinemann, Boston, MA. Vol. 1, p 974).
Potential Gas Byproducts
- Hydrocarbons
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