Reactivity Documentation
Azo, Diazo, Azido, Hydrazine, and Azide Compounds |
mixed with |
Sulfides, Inorganic |
Summary
- Explosive: Reaction products may be explosive or sensitive to shock or friction
- Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive
Details
Azo, Diazo, Azido, Hydrazine, and Azide Compounds
is a reactive group.
Sulfides, Inorganic
is a reactive group.
Reactivity Predictions (for each pair of reactive groups)
Azo, Diazo, Azido, Hydrazine, and Azide Compounds
mixed with
Sulfides, Inorganic
Sulfides, Inorganic
Hazard Predictions
- Explosive: Reaction products may be explosive or sensitive to shock or friction
- Intense or explosive reaction: Reaction may be particularly intense, violent, or explosive
Na2S or NaHS react violently with diazonium salts (Lewis, R.J., Sr. 1992. Sax's Dangerous Properties of Industrial Materials, 8th Edition. New York: Van Nostrand Reinhold. pp. 2105, 3144), generating explosive solids (Graebe, C. et al. 1882. Berichte. 15:1683.; Tomlinson, W.R. 1957. Chemical and Engineering News 29:5473).
CS2 forms heat and shock-sensitive explosive salts with metal azides (Mellor, J.W. 1947. Mellor's Comprehensive Treatise on Inorganic and Theoretical Chemistry. Longmans, Green and Co Ltd., Volume 8. pp. 338; Lewis, R.J., Sr. 1992. Sax's Dangerous Properties of Industrial Materials, 8th Edition. New York: Van Nostrand Reinhold. pp. 698.), and reacts violently with NaN3 (Lewis, p. 3064).