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Hazard Predictions

• Corrosive: Reaction products may be corrosive
• Generates gas: Reaction liberates gaseous products and may cause pressurization
• Generates heat: Exothermic reaction at ambient temperatures (releases heat)
• Toxic: Reaction products may be toxic

Hydrazine reacts with chlorosilanes to form silylhydrazides (compounds with a Si-N bond) with the release of HCl (Wannagat, U. and Meier, S., Zeitschrift fuer Anorganische und Allgemeine Chemie, Volume 392, Issue 2, Pages 179-87, 1972).

Both chlorosilanes and azo compounds can be highly reactive, so extreme caution should be used when dealing with a mixture of these two types of compounds. Further research of comparable examples in the literature or very small scale, carefully controlled experiments may be needed to fully assess compatibility.

Potential Gas Byproducts

• Hydrogen Chloride (HCl)
• Acid Fumes