Dirt/Earth
Examples of this absorbent type include soil and dirt. The following categories of chemicals have been known to react (that is, are incompatible ) with Dirt/Earth:
Category: Hydrazine, Hydrazine Derivatives, and Amines
- Reason for Concern:ÌýThese absorb strongly to organic material in dirt, releasing significant amounts of heat. The heat generated by this process can build up and cause the temperature to rise above the absorbed chemical's flash point —possibly resulting in a fire or explosion . Hydrazine, many hydrazine derivatives, and many amines are highly flammable and some are explosive.
- Examples:ÌýHydrazine; Trimethylamine; Diphenylamine
- Reactive Groups:ÌýAmines, Aromatic; Amines, Phosphines, and Pyridines; Azo, Diazo, Azido, Hydrazine, and Azide Compounds
Category: Hydrofluoric Acid
- Reason for Concern:ÌýHydrofluoric acid may react exothermically with the silicate structure in these absorbents. Aqueous solutions of other inorganic fluorides could also contain hydrofluoric acid, and so would react similarly with these absorbents.
- Examples:ÌýHydrofluoric acid; Ammonium bifluoride solution; Sodium fluorosilicate solution; Boron trifluoride diethyl etherate
- Reactive Groups:ÌýFluoride Salts, Soluble
Category: Reactive Monomers
- Reason for Concern:ÌýActive sites within these absorbents, including impurities, may catalyze exothermic , uncontrolled polymerization of monomers , leading to a thermal runaway. This could result in a fire or explosion.
- Examples:ÌýStyrene; Divinylbenzene (DVB); Vinylbenzyl chloride (VBC); Epoxide monomers (ethylene oxide, propylene oxide, etc.)
- Reactive Groups:ÌýAcrylates and Acrylic Acids; Conjugated Dienes; Epoxides; Hydrocarbons, Aliphatic Unsaturated; Polymerizable Compounds
Category: Water-Reactive 365betÓéÀÖ
- Reason for Concern:ÌýDirtÌýoften contains moisture, which could pose a hazard if it isÌýused to clean up water-reactive chemicals. Many water-reactive chemicals release toxic or corrosive gases and generate heat when they come into contact with even small amounts of water.
- Examples:ÌýMethyl isocyanate; Acetyl chloride; Acetic anhydride; Phenyltrichlorosilane
- Reactive Groups:ÌýAcid Halides, Sulfonyl Halides, and Chloroformates; Anhydrides; Chlorosilanes; Halogenating Agents; Isocyanates and Isothiocyanates; Thiocarbamate Esters and Salts/Dithiocarbamate Esters and Salts